Publications

Recent Refereed Journal Articles

• Yacyshyn M, Applegarth L, Cox JS, Tremaine PR (2022) Deuterium Isotope Effects on the Second Ionization Constant of Aqueous Sulfuric Acid from 25 °C to 200 °C using Raman Spectroscopy. Solution Chem. (In press)
• Fandiño O, Cox JS, McGregor C, Conrad J, Liao K, Tremaine PR (2021) Carbon Dioxide Contamination of Aqueous Morpholine Solutions and Effects on Secondary Coolant Chemistry Under CANDU Conditions. Nucl. Tech., 208, 192-201.
• Binkley S, Fandiño O, Cox JS, Tremaine PR (2021) Standard Partial Molar Heat Capacities and Volumes of Aqueous N,N-Dimethylethanolamine and N,N-Dimethylethanolammonium Chloride from 283.15 to 393.15 K, and Ionization Constants to 598.15 K.  J. Chem. Eng. Data 2021, 66, 11, 4180–4192.
• Conrad J, Tremaine P. (2021) Third Dissociation Constant of Phosphoric Acid in H₂O and D₂O from 75 to 300 °C at p = 20 MPa using Raman Spectroscopy and a Titanium-Sapphire Flow Cell. Phys. Chem. Chem. Phys. 23, 10670 – 10685.
• Arcis H, Ferguson J, Cox JS, Tremaine PR (2020) The Ionization Constant of Water at Elevated Temperatures and Pressures: New Data from Direct Conductivity Measurements and Revised Formulations from T = 273 K to 674 K and p = 0.1 MPa to 31 MPa. J. Phys. Chem. Ref. Data 43:033103.  See also accompanying ‘Editor’s Pick’ Scilight.
• J. Conrad, S. Sasidharanpillai, P.R. Tremaine, The Second Dissociation Constant of Carbonic Acid in H₂O and D₂O from 150 to 325 °C at p = 21 MPa using Raman Spectroscopy and a Sapphire-Windowed Flow Cell. J. Phys. Chem. B, 124(13): 2600-2617 (2020).
• Alcorn CD, Cox JS, Applegarth LMSGA, Tremaine PR (2019). Investigation of Uranyl Sulfate Complexation under Hydrothermal Conditions by Quantitative Raman Spectroscopy and Density Functional Theory. J. Phys. Chem. B. 123(34):7385–7409 .
• Sasidharanpillai S, Arcis H, Trevani L, Tremaine PR (2019). Triborate Formation Constants and Polyborate Speciation under Hydrothermal Conditions by Raman Spectroscopy using a Titanium/Sapphire Flow Cell. J. Phys. Chem. B. 123(24):5147-5159.
• McGregor C, Al-Abdul-Wahid MS, Robertson V, Cox JS, Tremaine PR (2018). Formation Constants and Conformational Analysis of Carbamate in Aqueous Solutions of 2-Methylpiperidine and CO2 from 283 K to 313 K by NMR Spectroscopy. J. Phys. Chem. B, 122: 9178-9190.
• Fandiño O, Sasidharanpillai S, Soldatov DV, Tremaine PR (2018). Carbamate formation in the system (2-Methylpiperidine + Carbon Dioxide) by Raman spectroscopy, X-Ray diffraction and computational Studies, J. Phys. Chem. B. 122(48):10880-10893.